Journal of Graphic Engineering and Design

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Vol. 8 No. 2 (2017): JGED - December 2017
Original scientific paper

Optimization of Cyan flexo dye removal by nano zero-valent iron using response surface methodology

Vesna Kecić University of Novi Sad, Faculty of Technical Sciences, Department of Graphic Engineering and Design, Novi Sad, Serbia
Đurđa Kerkez University of Novi Sad, Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Novi Sad, Serbia
Miljana Prica University of Novi Sad, Faculty of Technical Sciences, Department of Graphic Engineering and Design, Novi Sad, Serbia
Sanja Rapajić University of Novi Sad, Faculty of Sciences, Department of Mathematics and Informatics, Novi Sad, Serbia
Anita Leovac Maćerak University of Novi Sad, Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Novi Sad, Serbia
Milena Bečelić-Tomin University of Novi Sad, Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Novi Sad, Serbia
Dragana Tomašević Pilipović University of Novi Sad, Faculty of Sciences, Department of Chemistry, Biochemistry and Environmental Protection, Novi Sad, Serbia

Published 2017-12-01

Keywords

  • cyan flexo dye,
  • nano zero valent iron,
  • decolorization,
  • response surface methodology,
  • optimization process

Abstract

  • Application of nano zero-valent iron (nZVI) as a catalyst in a decolorization process is a simple and sensitive method for Cyan flexo dye removal from the aqueous solution. In this paper, a central composite design (CCD), under the response surface methodology (RSM), was applied in order to optimize experimental conditions of the Cyan removal from aqueous solution. The influence of four independent variables was studied: nZVI dosage (5–45 mg L-1), initial dye concentration (2–14 g L-1), pH (2–10) and removal time (20–100 min), in order to build second order quadratic model and to predict the responses. The highest removal percent of 96.35% was attained, and the optimum parameters are achieved after 1h/24h precipitation: nZVI dosage (5/45 mg L-1), initial dye concentration (2/14 g L-1), removal time (20/100 min) and pH (2/10). The Cyan removal efficiency of 38% and 62% were estimated under optimized experimental conditions.